Alkenyl succinic anhydride.

Alkenyl succinic anhydride (ASA) sizing is dominating over other sizing processes due to its high reactivity and economy. The shelf life of conventionally used cationic starch (CS) stabilized ASA emulsion is 20−25 min. In our previous study, the ASA emulsion was found to be stable up to 4 h using anionic polyacrylamide (APAM) as …Abstract. Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the …Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists ...The alkenyl succinic anhydrides (ASA) are made by heating a mixture of maleic anhydride (MA) and aliphatic olefin at a temperature of about 175°-275° C. The molecular weight of the olefin can vary widely depending upon the intended use of the ASA. paper size ASA have an alkenyl group of about 12-22 carbon atoms.DOI: 10.1016/j.ces.2020.116407 Corpus ID: 233528964; Stabilization of the emulsion of Alkenyl Succinic Anhydride (ASA) in water using cellulose nanofibrils @article{Arancibia2021StabilizationOT, title={Stabilization of the emulsion of Alkenyl Succinic Anhydride (ASA) in water using cellulose nanofibrils}, author={Fernando Arancibia and Eduardo Izquierdo and Miguel Pereira}, journal={Chemical ...

Alkenyl succinic anhydride (ASA) sizing is dominating over other sizing processes due to its high reactivity and economy. The shelf life of conventionally used cationic starch (CS) stabilized ASA ...

Alkenyl succinic anhydrides (ASA) have been prepared by ene-reaction of high-oleic Agro-Industrielle UMR 1010. INRA/INP-ENSIACET, Toulouse, France sunflower oil methyl esters with maleic anhydride in a 50% xylene medium. Response surface methodology (RSM) was used to investigate the influence of two factors: reaction temperature and molar ratio ...OxyContin maker Purdue Pharma has a patent for a form of opioid addiction treatment, which means it could profit from combatting the scourge. Richard Sackler, whose family owns Pur...

Jun 29, 2023 · Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists still have differing views on how ASA interacts with cellulose. Several experiments were conducted to bring more clarity to the ASA sizing mechanism, especially on the contentious question of ASA ... Alkenyl succinic anhydride (ASA) is an internal sizing chemical, normally applied in paper and board making at roughly neutral pH. For the paper and paperboards which have huge proportion of secondary fibers and mechanical cellulosic pulp, ASA has the advantage in sizing.Sizing performance of alkenyl succinic anhydride (ASA) emulsion stabilized by polyvinylamine macromolecules. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2018, 539, 132-139. DOI: 10.1016/j.colsurfa.2017.12.014. Qi Zhao, Wenxia Liu, Guodong Li, Lucian A. Lucia, Huili Wang, Dehai Yu. Succinic Anhydride. 113 Alkenyl succinic anhydrides (extensively used in the papermaking industry as paper sizing agents when manufactured by reaction of maleic anhydride with C14–C22 i-olefins) have been prepared by the ene reaction of the methyl esters of high-oleic sunflower oil with maleic anhydride in a 50% xylene medium.

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Succinic anhydride, is an organic compound with the molecular formula (CH 2 CO) 2 O. This colorless solid is the acid anhydride of succinic acid . Preparation. In the …

Oct 19, 2021 ... The group can be described as succinic anhydrides with various alkyl chain lengths as result of the reaction of maleic anhydride with ...The Money Channel contains articles that answer all of your financial questions. Check out the HowStuffWorks Business and Money Channel. Topics to Explore: Advertisement Advertisem...Medicine Matters Sharing successes, challenges and daily happenings in the Department of Medicine ARTICLE: Racial Disparities in Cardiovascular Complications With Pregnancy-Induced...Alkenyl succinic anhydrides (ASA) were prepared by an-ene reaction of n-alkyl (C1 to C5) oleates with maleic anhydride. The purified compounds were characterized by FTIR, 1H NMR, and MS analytical methods to elucidate their structures. Their physicochemical properties were systematically studied and found to depend on the length of the alkyl radical. Structure-property relations were ...A process for the preparation of an alkenyl-substituted succinic anhydride wherein the alkenyl substituent has a number average molecular weight of from about 500 to 5000 and the average number of succinic groups per alkenyl group is greater than 1.2 which comprises: (a) reacting a polyolefin having an alkylvinylidene isomer content of less than about 10 percent and a number average molecular ...Alkenyl succinic anhydride (ASA) sizing is dominating over other sizing processes due to its high reactivity and economy. The shelf life of conventionally used cationic starch (CS) … Cellulosic fiber is hydrophilic in nature and making it hydrophobic represents a process called sizing in papermaking.The optimal reaction conditions for obtaining the maximal yield (around 95%) of alkenyl succinic anhydride from methyl oleate were 235C, a molar ratio of 1.5, and a reaction lasting 8 h. However ...

In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted at 120 °C using dimethyl sulfoxide as a solvent, with conversions better than 88%.Alkenyl succinic anhydride (ASA) sizing is dominating over other sizing processes due to its high reactivity and economy. The shelf life of conventionally used cationic starch (CS) stabilized ASA emulsion is 20-25 min. In our previous study, the ASA emulsion was found to be stable up to 4 h using anionic polyacrylamide (APAM) as …Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsification of ASA using cationic starch is conventionally practiced because of the low shelf life of ASA emulsion. We synthesized Janus particles by surfactant-free seeded polymerization to stabilize ASA emulsion. The morphology evolution and anisotropic compositions of Janus ...Alkenyl succinic anhydride (ASA) gives sizing features efficiently to papersheet by being added to pulp suspensions as cationic ASA emulsions. Although the reactive structure of ASA is necessary for paper sizing, the previous paper revealed that alkenyl succinic acid (ASAcid), the hydrolyzed form of ASA, is the predominant component present in ...Alkenyl succinic anhydrides (ASA) were prepared by an-ene reaction of n-alkyl (C 1 to C 5) oleates with maleic anhydride.The purified compounds were characterized by FTIR, 1 H NMR, and MS analytical methods to elucidate their structures. Their physicochemical properties were systematically studied and found to depend on the length of the alkyl …

Sizing performance of alkenyl succinic anhydride (ASA) emulsion stabilized by polyvinylamine macromolecules. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2018, 539, 132-139. DOI: 10.1016/j.colsurfa.2017.12.014. Qi Zhao, Wenxia Liu, Guodong Li, Lucian A. Lucia, Huili Wang, Dehai Yu.

Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield, and fuel additives industries. In this paper we investigate the link between the physical properties of alkenyl succinic anhydrides and the identities of their linear alkyl olefin precursors.Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists ...Jun 1, 2017 · Stabilizing alkenyl succinic anhydride (ASA) emulsions using fine particles instead of cationic starch have attracted much attention in recent years. Herein, starch nanocrystals (SNCs) made from maize starch by H 2 SO 4 hydrolysis were used to co-stabilize ASA emulsions with fluorescent carbon dots (CDs) made hydrothermally from gelatin. The invention discloses a preparation method of alkenyl succinic anhydride. The preparation method comprises the following steps: mixing C16 internal olefin and C18 internal olefin each of which the purity is above 95% to form an internal olefin mixture, wherein the mass ratio of C16 internal olefin to C18 internal olefin is 1: (0.5-3); …Get ratings and reviews for the top 6 home warranty companies in Springfield, MA. Helping you find the best home warranty companies for the job. Expert Advice On Improving Your Hom...Alkenyl succinic anhydrides ( ASA) are derivatives of succinic anhydrides. One H of the succinic anhydride ring is replaced with an iso- alkenyl chain (C 14 to C 22 ). ASA's are colorless and usually viscous liquids. They are widely used, especially in surface sizing of paper, paperboard, and cardboard, as well as in the hydrophobicization of ...

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2 -Dodecenyl succinic anhydride is classified as a severe skin irritant, Category 2, according to Regulation EC No. 1272/2008. The substance is classified as an eye irritant, Category 2, by "reading-across" from tetrapropenyl succinic anhydride, a member of the C8 -12 Alkenyl Succinic Anhydride category.

Alkenyl succinic anhydride (ASA) is a widely used paper sizing agent that is applied in the form of oil-in-water (o/w) emulsions in order to impart a water-resistant character to the resulting paper.What to watch for today What to watch for today Manufacturing boosts GE’s profits. The US industrial titan, widely watched because of the worldwide market for its diverse products,...We list the places online and nearby that will let you place purchases on layaway and pay over time. Find options for furniture, jewelry, and more. Disclosure: FQF is reader-suppor...The invention discloses a preparation method of alkenyl succinic anhydrides (ASA). The preparation method comprises the following steps of: mixing raw materials (internal olefins and maleic anhydride in the molar ratio of 1.0 to 4.0), reacting the raw materials for 10-20 hours by using silica gel or silicate as a catalyst at a reaction temperature of 150 …Earthstone Energy News: This is the News-site for the company Earthstone Energy on Markets Insider Indices Commodities Currencies StocksAbstract. Alkenyl succinic anhydrides having a decreased amount of tar and color bodies are made by the reaction of an olefin with maleic anhydride in the presence of a tri-orthoalkylphenyl phosphite and optionally a hindered phenolic antioxidant such as 2,4,6-tri- (3,5-di-tert-butyl-4-hydroxybenzyl) mesitylene.Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists still have differing views on how ASA interacts with cellulose. Several experiments were conducted to bring more clarity to the ASA sizing mechanism, especially on the contentious question of ASA ...Features. · Alkenyl succinic anhydride having an alkenyl group having 15 carbon atoms. · The resins cured with this product has excellent electrical properties and flexibility. · This product is also easy to handle because it has low viscosity and long pot life (usable period). · Curing agents for epoxy resins.Mar 4, 2019 ... Alkenyl succinic anhydride (ASA) is an alkaline sizing agent most widely used in a number of alkaline paper grades. ASA is also known as a ...As of 2022, the global Alkenyl Succinic Anhydride (ASA) market was estimated at USD 203.82 million, and it’s anticipated to reach USD 299.58 million in 2028, with a CAGR of 6.63% during the ...

Alkenyl succinic anhydride from methyl oleate was isolated by column chromatography and analyzed by IR, 1 H- and 13 C-NMR and MS. The optimal reaction conditions for obtaining the maximum yield of alkenyl succinic anhydride from methyl oleate in the experimental domain (80%) were 210-220 °C and a maleic …@article{Sato2016SurfaceMO, title={Surface modification of cellulose nanofibers with alkenyl succinic anhydride for high-density polyethylene reinforcement}, author={Akihiro Sato and Daisuke Kabusaki and Hiroaki Okumura and Takeshi Nakatani and Fumiaki Nakatsubo and Hiroyuki Yano}, journal={Composites Part A-applied Science and …Instagram:https://instagram. smithsonian aerospace museum Alkenyl Succinic Anhydride (ASA) Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under neutral/alkaline conditions (at pH’s in the range of 7.5-8.5) in the 1960’s by O. Wurzburg and E. Mazzerella of the National Starch and Chemical Company [1].Product name : Succinic anhydride Product Number : 239690 Brand : Aldrich Index-No. : 607-103-00-5 CAS-No. : 108-30-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances Uses advised against : The product is being supplied under the TSCA R&D Exemption ... nyc parking fine payment Earthstone Energy News: This is the News-site for the company Earthstone Energy on Markets Insider Indices Commodities Currencies Stocks calouste gulbenkian museum Those results indicate that this surface strategy with DMSO as the pre-swelling solvent and the long-chain alkenyl succinic anhydride as the acylants (especially OSA) is particularly feasible for improving the properties of various types of BC films, which display great potential to be used in value-added applications, such as food packaging or biomedical …The Money Channel contains articles that answer all of your financial questions. Check out the HowStuffWorks Business and Money Channel. Topics to Explore: Advertisement Advertisem... forex simulator Mar 20, 2013 · Alkenyl succinic anhydride (ASA) is a commercial product from Dixie Chemical Co., Inc. It is light-amber liquid at room temperature, being composed of more than 70 wt% of hexadecenylsuccinic anhydride (HDSA, C 20 H 34 O 3 ), less than 25 wt% of octadecenylsuccinic anhydride (ODSA, C 22 H 38 O 3 ) and less than 2.5 wt% of mixed C15–20 olefins ... text apps free Kemira Oyj (Helsinki, Finland) announced a significant investment in the production of alkenyl succinic anhydride sizing agent (ASA) in China. ASA is one of the most effective and cost-efficient sizing agents for improving water-resistance in paper and packaging board. This investment into an additional, third production line at the … legit online casinos Alkenyl Succinic Anhydride (ASA) is sizing agent that is applied as an aqueous emulsion during the papermaking process to improve paper’s hydrophobicity. However, its application becomes difficult as the emulsion quickly destabilizes due to the coalescence phenomenon and the high reactivity of ASA with water.Alkenyl succinic anhydrides (ASA) have been prepared by ene‐reaction of high‐oleic sunflower oil methyl esters with maleic anhydride in a 50% xylene medium. Response surface methodology (RSM) was used to investigate the influence of two factors: reaction temperature and molar ratio between maleic anhydride (MA) and methyl esters (SME). … youtube viewer Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsification of ASA using cationic starch is conventionally practiced because of the ...Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists ...Alkenyl succinic anhydride (ASA) is one of the most prominent paper sizing agents worldwide. Commercial products start from isomerized C16-18 olefins with certain distribution of the double bond along the alkyl chain. This distribution is then found again in the product ASA which renders mechanistic studies on ASA binding to the cellulose surface difficult. For studies on ASA reactivity ... tamiami trail florida Films obtained from pristine tree gums are often brittle, hygroscopic, and lack mechanical strength. This study focuses on the chemical modification of gum kondagogu using long-chain alkenyl groups of dodecenyl succinic anhydride (DDSA), an esterifying agent that introduces a 12-carbon hydrophobic chain to the kondagogu structure. wip fm live Usually, when you get a refund from the IRS, you overpaid on your taxes throughout the year. However, you can still receive more money back than you paid to the IRS in the form of ... diry queen Octenyl succinic anhydride is an unsaturated cyclic anhydride that undergoes esterification with hydroxyl containing species under basic conditions. Due to the esterification, the addition of hydrophobic carbon chains and hydrophilic carboxylate groups to the fibers simultaneously increases their amphiphilicity (Xiao et al., 2019). Phthalic anhydride (PA) is a white crystalline compound used to manufacture plasticizers, pigments, dyes and resins. One major consumer of PA is the phthalate plasticiser industry, the products of which are used to produce flexible plastic products such as wire & cable applications, hoses, pipes, coated fabrics, roofing membranes and swimming pool liners. where to watch a dogs purpose Alkenyl Succinic Anhydride (ASA) was introduced as a sizing agent in papermaking in 1963 by Wurzburg and Mazzarella [1]. ASA is an organic compound with cyclic dicarboxylic anhydride and a tetrafurandione (Figure1). The chemical is light yellow color, oil-like, non-soluble in water, and liquid at room temperature [2,3].The succinic anhydride reaction with proteins is considered to specifically occur at the free amino groups of proteins, hence replacing the amino group (NH 3 +), at neutral pH with NHCOCH 2 CH 2 COO function [55]. A similar mechanism can be considered for alkenyl-substituted succinic anhydride.